Why Does Water Have High Surface Tension?

Water’s Molecular Blueprint

Water is made up of molecules, each containing one oxygen atom bonded to two hydrogen atoms. Oxygen has a stronger pull on the shared electrons, a property known as electronegativity, drawing them closer to itself. This unequal sharing creates a slight negative charge on the oxygen atom and slight positive charges on the hydrogen atoms. This uneven distribution of charge makes the water molecule polar, with distinct positive and negative ends. Polarity is foundational to water’s unique properties.

The Role of Hydrogen Bonds

The polarity of water molecules leads to a specific type of attraction between them, known as hydrogen bonds. A hydrogen bond forms when the partially positive hydrogen atom of one water molecule is attracted to the partially negative oxygen atom of an adjacent water molecule. While an individual hydrogen bond is relatively weak compared to the bonds within a single water molecule, their collective strength is substantial. Water molecules constantly form, break, and reform these hydrogen bonds. This continuous network creates strong cohesive forces, holding water molecules together.

Forces at the Water’s Surface

The strong cohesive forces from hydrogen bonds manifest differently based on a water molecule’s location. Molecules deep within the water are surrounded by other water molecules and experience attractive forces equally from every side. This balanced pulling results in no net force.

However, surface water molecules are in a different situation. They are surrounded by other water molecules below and to the sides, but none above them. Consequently, these surface molecules experience a net inward pull from molecules beneath and to their sides. This unbalanced inward force pulls surface molecules inward, minimizing the liquid’s surface area, creating a stretched, elastic film known as surface tension.

Surface Tension in Action

Water’s high surface tension allows for several noticeable phenomena. For instance, small insects like water striders can glide across a pond without sinking. Their lightweight bodies distribute their weight over a large enough area, allowing the water’s surface tension to support them. Water drops tend to form nearly spherical shapes when falling or resting on a non-absorbent surface, as surface tension minimizes their surface area. Additionally, objects denser than water, such as a paperclip, can sometimes float on the surface if carefully placed, as the surface tension film can support their weight.