What Makes Coke and Mentos Explode?

The eruption of soda when Mentos candies are dropped into it is a common phenomenon. This display, often seen in science demonstrations, is not the result of a chemical explosion. Instead, it is an example of a rapid physical reaction without forming new chemical compounds. Understanding this spectacle involves exploring the properties of carbonated beverages and the unique characteristics of the candy.

Understanding Carbonation

Carbonated beverages contain dissolved carbon dioxide (CO2) gas, giving them their fizz. CO2 is infused under high pressure during bottling. When the bottle is sealed, the gas remains dissolved, creating a supersaturated solution, holding more CO2 than normal at atmospheric pressure.

The dissolved CO2 constantly attempts to escape, but the liquid’s surface tension acts as a barrier. Water molecules attract each other, forming a tight connection around each gas bubble and resisting its expansion. This cohesive force traps the gas.

When a carbonated drink is opened, the pressure above the liquid is released, allowing the dissolved CO2 to escape. This slow release explains why an opened soda gradually goes flat as gas bubbles form and rise to the surface. The process of bubble formation requires energy to overcome the water’s surface tension.

The Mentos Effect

Mentos candies trigger the rapid release of CO2 due to their unique surface properties, providing nucleation sites, which are microscopic points where gas bubbles can easily form. The surface of a Mentos candy is not smooth; it is covered with countless tiny pits and irregularities.

These microscopic cavities provide locations for dissolved carbon dioxide to gather and form gas bubbles. Less energy is required for new bubbles to form and expand, accelerating the rate at which CO2 escapes from the supersaturated liquid.

The composition of Mentos also plays a role beyond just surface roughness. While some theories suggested ingredients like gum arabic or gelatin significantly reduce surface tension, experiments indicate the physical surface structure is the primary factor. Furthermore, Mentos candies are dense, causing them to sink quickly through the soda. This rapid descent allows the candy to interact with a large volume of carbonated liquid, maximizing exposed nucleation sites.

The Eruption Mechanism

When Mentos candies are dropped into a carbonated beverage, the numerous nucleation sites on their surface facilitate the rapid formation of CO2 bubbles. As these bubbles form, they expand and rise to the surface, drastically reducing the liquid’s surface tension.

This reduction allows even more dissolved carbon dioxide to escape with minimal resistance. The rising bubbles collect, creating a dense foam that pushes the liquid upward. The narrow opening of a soda bottle further intensifies this effect, channeling the expanding foam into a geyser.

The entire process is a physical reaction. It is a very fast phase change, where dissolved carbon dioxide transforms into free gas bubbles, forcing the liquid out. The impressive fountain is a direct consequence of the sudden release of this trapped gas.