What Is the pH of Muriatic Acid?

Muriatic acid is a potent chemical used in various household and industrial settings. Its strength and corrosive nature make it effective for many tasks, requiring a thorough understanding of its properties and appropriate handling procedures.

Understanding Muriatic Acid: pH and Properties

Muriatic acid is hydrochloric acid (HCl), a strong mineral acid. It is an aqueous solution of hydrogen chloride gas dissolved in water. The pH of muriatic acid is typically less than 1.0, indicating its high acidity. This low pH means it readily releases hydrogen ions when dissolved in water, making it highly corrosive.

Its corrosive properties allow it to dissolve many substances, making it effective in various cleaning and industrial processes. Muriatic acid is commonly available in concentrations from 14.5% to 29% hydrochloric acid, though industrial grades can be higher. It can appear clear to slightly yellowish and has a distinctive pungent, irritating odor.

Common Applications

Muriatic acid’s strong acidic nature makes it suitable for numerous cleaning and surface preparation applications. It is frequently used for etching concrete, a process that creates a rough surface to improve adhesion for coatings or sealants. This acid effectively removes dried cement products, such as mortar, concrete, and grout, from masonry surfaces like bricks and stones.

Muriatic acid is also widely applied in pool maintenance to adjust water chemistry. It helps to lower high pH levels and total alkalinity in swimming pools, ensuring the water remains balanced for swimmer comfort and chlorine effectiveness. This acid can also be used for rust removal, particularly from stainless steel, by dissolving the iron oxides that form rust. It is also useful for general heavy-duty cleaning of tough stains, mold, and mildew.

Safe Handling and Storage

Given its highly corrosive nature, handling muriatic acid requires strict safety precautions. Personal protective equipment (PPE) is essential, including chemical-resistant gloves, eye protection like goggles or a face shield, and protective clothing such as long sleeves, pants, and a chemical-resistant apron. Adequate ventilation is also necessary to avoid inhaling its irritating fumes, so it should be used outdoors or in a well-ventilated area, or under a fume hood.

When diluting muriatic acid, always add the acid slowly to water, never the other way around. Adding water to concentrated acid can cause a vigorous, heat-releasing reaction that may result in splashing and burns. Use only acid-resistant plastic containers for mixing and application.

For storage, keep muriatic acid in its original, tightly sealed container in a cool, dry, and well-ventilated location. It should be stored away from incompatible materials, including metals, oxidizers, organic materials, and alkaline substances, as dangerous reactions can occur. Store the acid securely out of reach of children and pets, and never mix it with other cleaning products, especially chlorine bleach, due to the risk of producing toxic gases. Proper disposal involves contacting a local hazardous waste facility rather than pouring it down drains.