What Is the Correct Chemical Formula for Barium Hydroxide Octahydrate?

Barium hydroxide octahydrate is an inorganic chemical compound used in various scientific and industrial processes. It exists as a crystalline solid, characterized by its interaction with water molecules. Understanding its full chemical makeup involves recognizing both its core components and the associated water.

The Chemical Formula Explained

The correct chemical formula for barium hydroxide octahydrate is Ba(OH)₂·8H₂O. Each part of this formula conveys specific information about the compound’s composition.
“Ba” represents barium, an alkaline earth metal from Group 2 of the periodic table. Barium is a highly reactive element, typically occurring within compounds where it exhibits a +2 oxidation state.
The “OH” denotes the hydroxide group, consisting of one oxygen atom covalently bonded to one hydrogen atom. The subscript “₂” indicates two hydroxide groups for every one barium ion, necessary to balance the +2 charge of the barium.
The dot (·) shows water molecules associated with the compound within its crystal structure. These “waters of hydration” are loosely attached, not part of the primary chemical bonds. “8H₂O” specifies eight water molecules associated with each formula unit of barium hydroxide.

The Significance of “Octahydrate”

The term “octahydrate” refers to the eight water molecules incorporated into barium hydroxide’s crystal structure. In chemistry, a “hydrate” contains water molecules as an integral part of its crystalline lattice, not just surface moisture.
The incorporation of water molecules influences a compound’s stability and physical properties. For barium hydroxide, the “octahydrate” form exhibits different characteristics compared to its anhydrous (water-free) counterpart. For instance, it has a lower melting point and dissolves more readily in water than anhydrous barium hydroxide. This water content also contributes to the compound’s overall molecular weight.

Common Uses and Properties

Barium hydroxide octahydrate typically appears as a white, odorless crystalline solid. It is hygroscopic, readily absorbing moisture from the surrounding air. This compound exhibits high solubility in water, forming a strong basic solution. Its melting point is approximately 78°C.
In analytical chemistry, barium hydroxide octahydrate is used for the titration of weak acids, particularly organic acids. Its clear aqueous solution is free of carbonate, which helps prevent errors during titration procedures. It also serves as a detection agent for carbonates and carbon dioxide.
Industrially, barium hydroxide octahydrate is used in:
Manufacturing other barium compounds
Refining sugar, particularly in the beet sugar industry
Adding to lubricating oils to neutralize acidic byproducts and enhance stability
Producing ceramics and glass
Wastewater treatment for sulfate removal