What Is the Chemical Composition of the Earth’s Crust?

The Earth’s crust is the planet’s rigid, outermost solid shell, representing a mere fraction of the total planetary volume. This layer is chemically distinct from the underlying mantle. The crust and the uppermost rigid part of the mantle form the lithosphere, the mechanically strong layer that constitutes the tectonic plates. The boundary separating the crust from the mantle is the Mohorovičić discontinuity (Moho), defined by a sharp increase in seismic wave speed.

Primary Chemical Building Blocks

The elemental makeup of the entire crust, considered as a weighted average, is overwhelmingly dominated by just a few elements. These “Big Eight” elements constitute approximately 98% of the crust’s total mass. Oxygen is the most abundant element, comprising roughly 46% of the crust by weight, primarily bonded with other elements to form minerals.

Silicon is the second most abundant element, making up about 28% of the mass, and its strong affinity for oxygen is the reason for the prevalence of silicate minerals. Following these two, the remaining six elements are Aluminum (around 8%), Iron (about 5%), and Calcium (approximately 4%). The final three elements in the group are Sodium, Potassium, and Magnesium, each making up between 2% and 2.5% of the crust’s mass.

These eight elements are not distributed uniformly, but their relative proportions define the bulk chemistry of this outermost layer. The differences in how these elements are concentrated become apparent when examining the two distinct types of crust found on Earth.

The Structural Difference Between Oceanic and Continental Crust

The Earth’s crust is structurally and chemically divided into two principal types: the thin, dense oceanic crust and the thick, less dense continental crust. This compositional difference is the primary reason for their distinct physical behavior and is crucial to the mechanics of plate tectonics. Oceanic crust is relatively thin, typically ranging from 5 to 10 kilometers in thickness, and is found beneath the ocean basins.

This oceanic crust has a mafic composition, a term derived from its high concentration of Magnesium and Iron. The main rock types are basalt and gabbro, which are dark-colored, silica-poor, and possess a relatively high density, averaging around 3.0 grams per cubic centimeter. The oceanic crust is constantly being created at mid-ocean ridges and destroyed at subduction zones, making it geologically young compared to its continental counterpart.

In stark contrast, continental crust is significantly thicker, with an average depth of about 35 kilometers, but it can reach up to 90 kilometers beneath major mountain ranges. This crust has a felsic composition, meaning it is rich in lighter elements such as Silicon and Aluminum. The principal rock type is granite, which is light-colored, silica-rich, and has a lower density, typically around 2.7 grams per cubic centimeter.

The lower density of continental crust prevents it from being easily subducted back into the mantle, allowing it to accumulate over billions of years and making it generally much older than oceanic crust. This difference in composition—felsic (rich in Si, Al, K, Na) versus mafic (rich in Fe, Mg)—causes continental masses to float higher on the mantle.

Common Mineral Families and Rock Types

The vast majority of the Earth’s crust, over 90% by volume, is composed of crystalline solids known as the silicate minerals. These minerals share a fundamental structural unit called the silica tetrahedron, which consists of a single silicon atom bonded to four oxygen atoms. The way these tetrahedral units link together determines the specific mineral’s structure and properties.

Within the silicates, the two most abundant mineral families are the feldspars and quartz. Feldspar, a complex group containing aluminum, silicon, and various alkali or alkaline earth metals, is the single most common mineral in the crust. Quartz, composed purely of silicon dioxide, is the second most abundant mineral and is particularly common in continental rocks due to its high silica content. Other significant silicate groups include micas, amphiboles, and pyroxenes.

Most crustal material is igneous in origin, formed from the cooling and solidification of molten magma or lava. Felsic rocks, such as granite, are characterized by lighter-colored minerals like quartz and potassium-rich feldspar. Conversely, mafic rocks, exemplified by basalt, are darker and contain minerals rich in iron and magnesium, such as pyroxene and calcium-rich plagioclase feldspar.