What Is Amylose Made Of? Structure and Function

Amylose is a common carbohydrate and a primary component of starch, which serves as an energy storage molecule in plants. It is a significant part of the human diet, providing insight into how our bodies process starchy foods.

The Basic Building Blocks of Amylose

Amylose is a polysaccharide, a large molecule made up of many glucose units linked together. The fundamental building block is glucose. These units are joined in a long chain through alpha-1,4 glycosidic bonds. The number of glucose subunits can range from a few hundred to many thousands.

Amylose’s Distinctive Linear Structure

Amylose is characterized by its largely unbranched, linear chain of glucose units. This linear structure differentiates it from other starch components. In solution, this long chain tends to coil into a helical shape, influenced by hydrogen bonds. This structure impacts amylose’s properties, affecting its solubility in water and its ability to form gels when cooked.

Role in Plants and Human Digestion

Amylose serves as a storage polysaccharide in plants, found in common starchy foods such as potatoes, rice, and corn. In human nutrition, amylose’s linear structure contributes to slower digestion compared to more branched starches. This slower breakdown leads to a more sustained release of glucose into the bloodstream, which can help manage blood sugar levels. A portion of amylose can resist digestion in the small intestine, reaching the large intestine where it acts as a fermentable fiber, known as resistant starch. Resistant starch can be fermented by gut bacteria, leading to the production of beneficial compounds like short-chain fatty acids. These compounds support gut health by nourishing gut cells, reducing inflammation, and potentially improving metabolic markers.

Amylose Versus Amylopectin

Starch is composed of two main types of polysaccharides: amylose and amylopectin. The primary difference lies in their molecular structure. Amylose is a linear, unbranched chain of glucose units linked by alpha-1,4 glycosidic bonds, forming a helical shape. In contrast, amylopectin is a highly branched molecule, featuring alpha-1,4 glycosidic bonds along its main chains and alpha-1,6 glycosidic bonds at its branching points. These structural differences affect their physical properties. Amylose is less soluble in water and forms firm gels, while amylopectin is more soluble and forms viscous, non-gelling pastes. The ratio of amylose to amylopectin varies by plant source, influencing the texture, digestibility, and other characteristics of starchy foods.