What Is Acrylonitrile Used For?

Acrylonitrile (AN) is a colorless, volatile organic liquid that serves as a foundational building block for many synthetic materials worldwide. It is fundamentally a monomer, meaning its molecules link together in long chains to form polymers. Its importance stems from the nitrile group in its structure, which imparts specific chemical properties highly desirable in industrial applications. This compound is manufactured in large quantities for use across the chemical industry.

The Foundation of Textile Production

One of the primary uses for Acrylonitrile is in the creation of synthetic textile fibers, specifically acrylic and modacrylic fibers. The polymerization of Acrylonitrile forms polyacrylonitrile (PAN), the main component of acrylic fiber, which is often marketed as a synthetic replacement for wool. These fibers are valued for their soft, lightweight feel and ability to retain warmth without adding significant bulk.

Acrylic textiles resist sunlight and general weathering, making them suitable for both indoor and outdoor applications. The material accepts dyes readily, allowing for vibrant and long-lasting colors in finished goods. Common products include sweaters, blankets, carpets, and various outdoor fabrics like awnings and marine covers. Modacrylic fibers are notably flame-resistant and display improved durability compared to standard acrylic, leading to their use in specialized protective textiles.

Key Component in Durable Plastics

Acrylonitrile is a crucial ingredient in the production of rigid, high-performance plastics, most notably Acrylonitrile Butadiene Styrene (ABS) and Styrene Acrylonitrile (SAN) resins. In these copolymers, the Acrylonitrile component enhances the material’s chemical resistance, rigidity, fatigue resistance, and surface hardness.

In the widely used ABS plastic, Acrylonitrile provides thermal and chemical stability, allowing the material to retain its shape and resist environmental damage. ABS is formed from three monomers: Acrylonitrile, butadiene (which adds significant impact resistance), and styrene (which provides a glossy surface finish). The resulting combination is a tough, versatile plastic used in products requiring high durability, such as automotive parts, protective casings, piping, and LEGO bricks.

Styrene Acrylonitrile (SAN) resins represent another major application where Acrylonitrile is combined with styrene but without the butadiene component. The absence of butadiene means SAN lacks the high impact resistance of ABS, but it gains superior clarity, stiffness, and dimensional stability. This makes SAN an ideal choice for transparent or translucent items. Examples of SAN products include food storage containers, blender jars, and specialized lenses for automotive instrument panels.

Specialized Industrial Applications

Acrylonitrile is integral to several other specialized industrial materials beyond textiles and rigid plastics. It is a component in the creation of Nitrile Butadiene Rubber (NBR), an elastomer that resists oil, fuel, and other chemicals. This resistance makes NBR popular for manufacturing protective gloves, seals, gaskets, and fuel hoses in the automotive and industrial sectors.

The compound also functions as a chemical intermediate. A significant portion of Acrylonitrile production is used to synthesize acrylamide, which is polymerized to create water-soluble polymers used in water treatment and enhanced oil recovery. Furthermore, Acrylonitrile is used in the creation of high-performance carbon fibers for composites in the aircraft, defense, and aerospace industries.