What Is a Salt in Chemistry?

In chemistry, a salt is a compound formed from positively charged ions (cations) and negatively charged ions (anions). These ions are held together by strong electrostatic forces, known as ionic bonds, resulting in a compound with no overall electrical charge. While table salt, or sodium chloride, is the most recognized example, the chemical definition encompasses a vast array of substances. Salts are fundamental to numerous chemical processes and everyday applications.

How Salts Are Formed

Salts form through a chemical reaction known as neutralization, where an acid reacts with a base. During this process, the positive ions from the base combine with the negative ions from the acid. For instance, hydrochloric acid reacts with sodium hydroxide to produce sodium chloride and water.

The nature of the acid and base involved determines the specific properties of the resulting salt. For example, the reaction between a strong acid and a strong base yields a neutral salt.

While neutralization is the primary method, salts can also arise from other chemical interactions. Alkali metals and halogens can combine directly to form salts.

Defining Characteristics of Salts

Salts exhibit several defining physical and chemical properties due to their ionic structure. Most salts are crystalline solids at room temperature. Their ions are arranged in a repeating, three-dimensional pattern, which results in distinct crystal shapes.

These strong ionic bonds also mean that salts have high melting points. For example, sodium chloride melts at 801 °C, requiring considerable energy to break the strong attractions between its ions. Salts are hard but brittle, meaning they can shatter when subjected to force, as this force can align like-charged ions, causing repulsion.

Salts are soluble in water, where they dissociate into their constituent ions. This dissociation allows salt solutions to conduct electricity effectively, making them good electrolytes. Similarly, molten salts can conduct electricity because their ions become mobile.

Salts in Our World

Salts are prevalent in various aspects of our daily lives, extending far beyond table salt. Sodium chloride, while a common seasoning and food preservative, also serves extensively in industry. It is a raw material for producing chemicals like sodium bicarbonate and chlorine, and is used in manufacturing soap and porcelain enamel.

Beyond sodium chloride, diverse salts find widespread applications. Calcium carbonate, for instance, is a component of limestone used in construction and found in antacids. Magnesium sulfate, known as Epsom salts, is utilized for muscle relaxation and in bath soaks. Potassium nitrate is a component in fertilizers and explosives.

Other examples include sodium bicarbonate, or baking soda, used in baking, as an antacid, and in fire extinguishers. Calcium chloride is employed as a drying agent and for dust control on roads. Sodium hypochlorite functions as a cleaning and bleaching agent, while alum assists in water treatment processes.

In biological systems, salts play a role in maintaining bodily functions. Ions from salts, often called electrolytes, maintain fluid balance within the body. They support nerve impulses, muscle contractions, and regulate blood pressure. Obtained through diet, these ions are necessary for cellular activities and overall physiological stability.