Is There Water on Mercury? The Evidence for Ice

Water ice exists on Mercury, a remarkable finding given that surface temperatures can reach a scorching 800 degrees Fahrenheit. The ice is not found in exposed areas but is concentrated in specific locations near the planet’s poles. This discovery provides new insights into how volatile materials, like water, can be delivered and preserved even in the solar system’s most extreme thermal environments.

The Polar Paradox: How Ice Survives

The existence of water ice on a planet experiencing such intense solar radiation is explained by a specific planetary geometry known as the “polar paradox.” This phenomenon is directly related to Mercury’s axial tilt, or obliquity, which is nearly zero—less than one degree. The minimal tilt means that the Sun’s angle above the horizon changes very little throughout the planet’s orbit.

This low obliquity prevents sunlight from ever reaching the floors of deep impact craters located near the north and south poles. These areas are known as permanently shadowed regions (PSRs). Within these craters, the temperature remains hundreds of degrees below freezing, creating extremely cold traps.

Temperatures in these PSRs can drop to a frigid -280 degrees Fahrenheit, cold enough for water molecules to condense and remain stable as ice. This deep-freeze environment allows water ice to persist for potentially billions of years.

Scientific Confirmation of Water Ice

The evidence for water ice on Mercury developed in two distinct stages, beginning with Earth-based observations. In the early 1990s, the Arecibo radio telescope detected unusually bright patches at Mercury’s poles, which were highly reflective of radar waves. These radar-bright signatures were consistent with what scientists would expect from water ice, although the evidence was not conclusive on its own.

Definitive proof came with the NASA MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission, which orbited the planet from 2011 to 2015. MESSENGER provided three independent lines of evidence confirming the presence of water ice. The Mercury Laser Altimeter (MLA) mapped the planet’s topography and confirmed that the radar-bright regions were located precisely within the permanently shadowed craters.

The spacecraft’s Neutron Spectrometer detected high concentrations of hydrogen in these polar areas. Since water ice contains hydrogen, this excess strongly suggested the presence of substantial water ice deposits. Thermal models confirmed that these shadowed regions were cold enough to maintain the ice, which is often buried beneath a thin, insulating layer of darker material.

Potential Origins of Mercury’s Water

The water ice found in Mercury’s polar cold traps likely originated from external sources over the planet’s history. The leading hypothesis suggests delivery via impacts from comets and water-rich asteroids. These icy bodies, remnants from the outer solar system, would have crashed into Mercury, releasing water vapor that subsequently migrated across the planet.

Once released, water molecules that drifted toward the poles were captured and frozen within the permanently shadowed regions. There is also a secondary theory proposing that some water could be produced locally on Mercury’s surface. This process involves protons from the solar wind impacting oxygen-bearing minerals in the planet’s soil.

This interaction generates small amounts of water that are then released into Mercury’s thin exosphere. These newly formed water molecules follow the same path, migrating and becoming trapped as ice in the polar craters. The accumulation of water from both external impacts and local production has resulted in significant ice deposits, estimated to be hundreds of billions to a trillion metric tons.