Is Obsidian Mafic or Felsic? Its True Chemical Makeup

Obsidian, a familiar dark volcanic glass, holds a surprising place in geology. Its deep, often jet-black appearance suggests a specific chemical makeup, but its true classification depends on its silica concentration. This article clarifies whether obsidian’s composition is classified as mafic or felsic.

Defining Mafic and Felsic Rocks

Igneous rocks, which form from cooled magma or lava, are classified primarily by their bulk chemistry, specifically their silica (SiO2) content. Felsic rocks are defined by a high silica content, typically greater than 65% by weight. They are rich in lighter elements like aluminum, potassium, and sodium.

The term “felsic” is a combination of “feldspar” and “silica,” reflecting the common minerals found in these rocks, such as quartz and feldspar. This high silica concentration generally results in rocks that are light in color, often white, pink, or light gray, with granite being the most common example.

In contrast, mafic rocks are characterized by a lower silica content, generally ranging from 45% to 55%. The name “mafic” is derived from “magnesium” and “ferric” (iron), indicating their abundance of heavier, darker elements. Mafic rocks are typically dark in color, appearing black or dark green, and include common types such as basalt and gabbro.

Obsidian’s Chemical Composition

Despite its dark coloration, a trait usually associated with mafic rocks, obsidian is classified as felsic. Chemical analysis consistently shows that obsidian is rich in silica, with content often ranging from 65% to over 70% by weight. This places it squarely in the felsic category alongside crystalline rocks like granite and rhyolite.

The high silica content directly influences the magma from which obsidian forms, leading to high viscosity. This thick, sticky melt inhibits the movement of atoms required to form organized crystal structures. Obsidian’s classification is therefore based on its underlying chemistry, not its surface appearance.

The Role of Texture and Appearance

The apparent contradiction of a dark-colored felsic rock is resolved by examining its unique texture and formation process. Obsidian is a natural volcanic glass, meaning it cooled so rapidly that atoms did not have time to organize into a crystalline structure. The absence of well-defined mineral crystals is why it is considered a glass and not a true mineral.

Felsic rocks are typically light because they are composed of light-colored minerals like quartz and feldspar. However, obsidian cools too quickly, preventing these minerals from crystallizing. The dark color is primarily caused by trace amounts of impurities, most commonly finely dispersed iron oxides like magnetite. These tiny iron-rich inclusions absorb light, giving the glassy structure its characteristic jet-black hue, despite the silica-rich bulk chemistry.