Is Gas a Byproduct of Diesel Fuel or Combustion?

It is common to wonder about the relationship between diesel fuel and “gas,” a term that can refer to either gasoline or gaseous emissions. This ambiguity often leads to questions about whether one fuel is a byproduct of the other, or if “gas” refers to the exhaust produced during combustion. This article clarifies the distinct nature of diesel fuel and gasoline, and explains the various gaseous byproducts that result from diesel engine operation.

Diesel and Gasoline: Separate Fuel Products

Both diesel and gasoline originate from crude oil, but they are distinct products of the refining process, not byproducts of each other. Crude oil undergoes fractional distillation, heated until it vaporizes. This mixture then enters a tall distillation tower.

Inside this tower, components of crude oil separate based on their boiling points. Lighter components with lower boiling points, such as gasoline, rise higher in the tower and condense at cooler temperatures near the top. Heavier components with higher boiling points, like diesel fuel, condense in lower, warmer sections. This process directly extracts gasoline and diesel as distinct fractions.

Chemically, gasoline consists of hydrocarbons with shorter carbon chains (4 to 12 carbon atoms per molecule), boiling between 30 and 210 degrees Celsius (86-410 degrees Fahrenheit). Diesel fuel is composed of longer hydrocarbon chains (10 to 20 carbon atoms), with a higher boiling point range of 170 to 360 degrees Celsius (338-680 degrees Fahrenheit), making it less volatile than gasoline.

Gaseous Emissions from Diesel Engines

When diesel fuel burns in an engine, it produces various gaseous and particulate byproducts that form the exhaust. The primary components of diesel exhaust by volume are nitrogen, oxygen, carbon dioxide, and water vapor. These are largely formed from the air used in the combustion process and the complete burning of the fuel.

Diesel combustion also generates harmful substances. Nitrogen oxides (NOx), which include nitric oxide (NO) and nitrogen dioxide (NO2), form when nitrogen and oxygen from the air react under the high temperatures and pressures inside the engine cylinders. Carbon monoxide (CO) and unburned hydrocarbons (HC) are also produced, primarily due to incomplete combustion of the diesel fuel.

Sulfur dioxide (SO2) can be present in diesel exhaust, originating from the sulfur content naturally found in diesel fuel. Diesel engines emit particulate matter (PM), a mixture of solid and liquid substances. This PM includes soot (elemental carbon), along with organic compounds, sulfates, and trace metals. These gaseous and particulate emissions are byproducts of diesel combustion, not fuel manufacturing.

Understanding the Question

The question “is gas a byproduct of diesel fuel or combustion?” can be interpreted in two ways, each with distinct answers. If “gas” refers to gasoline, then gasoline is not a byproduct of diesel fuel production. Both are separate, primary products obtained directly from crude oil through fractional distillation, each with distinct chemical compositions and boiling points.

However, if “gas” refers to gaseous emissions, then various gases are byproducts of diesel combustion. Burning diesel fuel in an engine produces exhaust gases, including carbon dioxide, water vapor, nitrogen oxides, carbon monoxide, and sulfur dioxide, along with particulate matter. The confusion often stems from the broad use of the term “gas” and a lack of distinction between fuel refining processes and the byproducts of engine operation.