Is Baking Soda and Vinegar an Exothermic Reaction?

Baking soda, known chemically as sodium bicarbonate, and vinegar, which is a dilute solution of acetic acid, are common household items frequently used in cooking, cleaning, and simple science experiments. These two ingredients are particularly popular for demonstrations that produce a noticeable fizzing reaction. A common question arises about the temperature change that occurs when they mix, prompting curiosity about the energy dynamics of this chemical interaction.

Understanding Chemical Energy Changes

A chemical reaction involves a process where one or more substances transform into different ones. During these transformations, energy is either absorbed or released, often as heat. Chemical reactions are categorized based on these energy changes.

An exothermic reaction is a chemical process that releases energy, typically in the form of heat, into its surroundings. In such reactions, the energy contained within the products is lower than the energy of the initial reactants, leading to an increase in the temperature of the surrounding environment.

Conversely, an endothermic reaction is a chemical process that absorbs energy, usually as heat, from its surroundings. This absorption of energy results in a decrease in the temperature of the mixture and its immediate environment. The energy of the products in an endothermic reaction is higher than that of the reactants.

The Baking Soda and Vinegar Reaction

The reaction between baking soda and vinegar is an endothermic process, meaning it absorbs heat from its surroundings. When sodium bicarbonate (NaHCO3) combines with acetic acid (CH3COOH), they produce carbon dioxide gas (CO2), water (H2O), and sodium acetate (CH3COONa).

Because heat is absorbed from the surroundings, the mixture feels noticeably cooler to the touch. This cooling sensation is a direct indication of the endothermic nature of the reaction.

How to Observe the Temperature Change

Observing the temperature change of the baking soda and vinegar reaction is a straightforward experiment anyone can conduct at home. To do this, simply pour some vinegar into a cup and then add a few teaspoons of baking soda. As the ingredients combine, you can immediately feel the outside of the cup.

Alternatively, a thermometer can be used to measure the temperature of the vinegar before adding the baking soda and then again during the reaction. You will notice a distinct drop in temperature, confirming the cooling effect. This simple observation provides tangible evidence that the reaction absorbs heat from its surroundings, characteristic of an endothermic process.