How Many Metalloids Are in the Periodic Table?

The periodic table organizes elements into categories like metals, nonmetals, and metalloids, which sit between the two. Asking “how many metalloids are there” seems like a simple question that should have a single, direct answer. The reality is that the boundary between categories is not a sharp line, but rather a transitional zone. This intermediate nature makes the count of metalloids complex and variable depending on the source consulted.

Defining Metalloids

Metalloids are chemical elements that exhibit physical and chemical properties falling between those of metals and nonmetals. Physically, many metalloids possess a metallic luster but are often brittle and poor structural materials, which is characteristic of nonmetals. Their most significant intermediate property is variable electrical conductivity. Most metalloids function as semiconductors, meaning they can conduct electricity under certain conditions, but not as efficiently as true metals. On the periodic table, these elements are found along the dividing line, often depicted as a “stair-step” line.

The Standard Count and List

In general chemistry education, the number of metalloids is typically presented as seven, though a core group of six elements is almost universally accepted. The six elements that nearly all sources agree upon are Boron (B), Silicon (Si), Germanium (Ge), Arsenic (As), Antimony (Sb), and Tellurium (Te). Silicon is the most famous metalloid due to its widespread technological use. Germanium and Arsenic reside firmly within this core classification, as does Boron. To reach the common count of seven, Polonium (Po) is frequently included, though its classification is highly debated. This seven-element list is often taught in introductory science courses as the standard number.

The Ambiguity in Classification

The number of metalloids varies because there is no official, universally binding definition from the International Union of Pure and Applied Chemistry (IUPAC). Classification relies on a collection of physical and chemical properties that transition gradually across the periodic table, not a single quantitative measure. This ambiguity results in different scientific authorities listing six, seven, eight, or even nine elements.

The debate often centers on marginal elements like Polonium (Po) and Astatine (At). Polonium is frequently included in the count of seven, but modern analyses suggest it behaves more like a true metal. Astatine is also sometimes listed as a metalloid, but its extreme radioactivity makes its bulk properties difficult to measure definitively. The criteria for inclusion can range from physical appearance and brittleness to complex electronic band structures.

Unique Characteristics and Applications

The unique position of metalloids allows for their most important technological application: their use as semiconductors. This property results from their intermediate electronic band structure, which permits the controlled flow of electricity. Unlike metals, which are always conductive, or nonmetals, which are insulators, metalloids can be chemically modified through a process called doping to adjust their conductivity precisely.

Silicon is the foundation of the modern electronics industry, forming the basis for integrated circuits, transistors, and microchips. Germanium plays a significant role in high-speed electronics and infrared optics. This ability to tune electrical flow also makes them indispensable in photovoltaic devices, where they convert sunlight directly into electrical energy in solar cells.

Other Applications

Beyond electronics, metalloids are utilized in various other ways that exploit their hybrid nature. Boron, for example, is a component in specialized borosilicate glass, which is prized for its resistance to thermal shock. Antimony is often added to lead alloys to improve their hardness and durability, making it useful in batteries and certain solders.