How Does Ozone Water Treatment Work?

Ozone water treatment purifies water by introducing ozone gas (O3). This powerful oxidizing agent reacts with and breaks down various pollutants, effectively destroying microorganisms and transforming complex organic compounds. The treatment is recognized for its ability to purify water without leaving chemical residues. This is because ozone rapidly converts back into oxygen after its work is done.

Understanding Ozone

Ozone is an inorganic molecule composed of three oxygen atoms, represented by the chemical formula O3. It exists as a pale blue gas with a distinct, pungent odor, often described as similar to chlorine or the fresh smell after a thunderstorm. Naturally, ozone is found in small amounts throughout the Earth’s atmosphere, with a higher concentration in the stratosphere, forming the ozone layer that absorbs harmful ultraviolet radiation.

In water treatment, ozone’s significance stems from its property as a powerful oxidizing agent. It readily accepts electrons from other substances, initiating chemical reactions that break down or inactivate them. This allows ozone to destroy bacteria, viruses, and other contaminants by chemically altering their structure.

The Mechanism of Ozone Water Treatment

Ozone water treatment begins with on-site ozone generation, as ozone is unstable and cannot be stored. Generators produce O3 by passing dry air or oxygen through a high-voltage electrical discharge. Another method uses ultraviolet (UV) light, which splits oxygen molecules, allowing them to recombine into ozone.

Once generated, the ozone gas is introduced into the water, where it quickly dissolves and initiates reactions with contaminants. Ozone’s purification action occurs primarily through two mechanisms: direct oxidation and indirect oxidation. Direct oxidation involves the ozone molecule (O3) directly reacting with pollutants by transferring an oxygen atom, breaking down their molecular structure. This pathway is often selective, targeting specific chemical bonds.

Indirect oxidation forms highly reactive free radicals, particularly hydroxyl radicals (OH•), when ozone decomposes in water. These hydroxyl radicals are even stronger oxidizers than ozone and react rapidly and non-selectively with a wide array of compounds. This dual mechanism ensures broad-spectrum purification by chemically transforming pollutants.

Contaminants Targeted by Ozone

Ozone is highly effective at inactivating bacteria and viruses by disrupting their cell membranes or damaging their genetic material. This includes common pathogens such as Escherichia coli, Bacillus bacteria, and various viruses, many destroyed within seconds.

Beyond bacteria and viruses, ozone is also capable of inactivating more resistant parasites like Giardia cysts and Cryptosporidium oocysts, which often pose challenges for other disinfectants. Organic compounds, including pesticides, pharmaceuticals, and substances causing undesirable tastes and odors, are also broken down by ozone. Furthermore, it oxidizes inorganic substances such as iron and manganese, converting them into solid particles that can be easily filtered out of the water.

Common Uses of Ozone Water Treatment

In municipal drinking water plants, ozone serves as a powerful disinfectant, reducing bacteria, viruses, and protozoa. It also helps remove color, improve taste, and reduce odors. This application often reduces the formation of harmful disinfection byproducts, which can occur with chlorine.

Industrial processes, including food and beverage, pharmaceutical, and wastewater treatment, frequently employ ozonation. It disinfects process water, removes pollutants like organic compounds and heavy metals from wastewater, and controls algae and biofilm growth in cooling towers.

Swimming pools and spas also benefit from ozone treatment, where it disinfects the water and reduces the need for high levels of chlorine, leading to fewer irritations for swimmers. It helps eliminate chloramines, which are responsible for the strong chemical smell and eye irritation commonly associated with chlorinated pools. Some residential water treatment systems also integrate ozone for disinfection and overall water quality improvement, offering a comprehensive solution for household water purification.