Why Do Mentos and Coke React? The Science Explained

The dramatic geyser created when Mentos candy is dropped into a bottle of soda is a popular demonstration. This powerful column of liquid erupts from the bottle due to specific physical interactions. Understanding this phenomenon involves exploring the properties of carbonated drinks and the unique characteristics of the candy that trigger such a forceful reaction.

Physical Reaction Fundamentals

The interaction between Mentos and carbonated beverages is a physical process, not a chemical one. No new chemical compounds are formed during the eruption; instead, existing components change their state or arrangement. Carbonated drinks contain dissolved carbon dioxide (CO2) gas, which is infused into the liquid under high pressure during manufacturing. This dissolved gas remains in solution as long as the pressure inside the sealed bottle is maintained. When the bottle is opened, the pressure above the liquid decreases, and the dissolved CO2 naturally seeks to escape, forming bubbles.

How Mentos Triggers the Eruption

Mentos candy plays a specific role in initiating the rapid release of carbon dioxide. Its surface, though seemingly smooth, is highly porous and rough on a microscopic level. These tiny imperfections act as “nucleation sites,” providing countless points where dissolved CO2 molecules can quickly gather and form bubbles. Estimates suggest a single Mentos candy can have millions of such cavities, typically measuring between 1 to 7 micrometers in size. Ingredients like gum arabic and gelatin in Mentos also reduce the soda’s surface tension, making it easier for carbon dioxide bubbles to form and detach from the nucleation sites, accelerating their growth and release. This combined effect of abundant nucleation sites and reduced surface tension allows for an exceptionally rapid generation of gas bubbles.

The Role of Carbonated Beverages

Carbonated beverages are essentially supersaturated solutions of carbon dioxide gas, meaning they contain more dissolved CO2 than would normally be possible at standard atmospheric pressure. The carbon dioxide is eager to escape from the liquid, and the Mentos simply provides the optimal conditions for this escape to occur almost instantaneously. Different types of carbonated beverages can produce varying reactions. Diet sodas, particularly Diet Coke, often yield a more dramatic fountain compared to their sugary counterparts. This enhanced effect is partly attributed to ingredients like aspartame and potassium benzoate present in diet sodas, which can further lower the liquid’s surface tension. The reduced stickiness of diet soda also makes cleanup easier after the demonstration.

Explaining the Explosive Fountain

The combined factors of Mentos and carbonated soda lead to a dramatic eruption. As Mentos candies sink rapidly through the soda, their rough surfaces activate millions of nucleation sites throughout the liquid, causing an almost instantaneous and widespread formation of carbon dioxide bubbles. The sheer volume of gas produced in such a short time is substantial; for instance, 12-15 grams of dissolved CO2 in a 2-liter bottle can expand to occupy up to 8 liters of space as a gas. This immense volume of rapidly expanding gas has nowhere to go but up and out through the narrow bottle opening. The continuous formation and upward movement of these bubbles create a chain reaction, pushing the liquid out with significant force, resulting in the characteristic fountain.