What Elements Are in the Oxygen Family?

The periodic table organizes all known chemical elements, providing a framework to understand their characteristics and interactions. Elements with similar chemical properties are arranged into vertical columns, often referred to as “groups” or “families.” This classification helps scientists predict how elements will behave and react with one another. These groupings are based on shared electron configurations, which largely dictate an element’s reactivity and bonding patterns.

The Chalcogen Group

The oxygen family, formally Group 16 of the periodic table, is known as the Chalcogens. This group includes six elements: Oxygen (O), Sulfur (S), Selenium (Se), Tellurium (Te), Polonium (Po), and Livermorium (Lv). While sharing fundamental similarities, their characteristics change progressively down the group, giving each element unique attributes.

Common Traits and Behavior

Chalcogens have six valence electrons in their outermost shell. This configuration influences their reactivity, as they tend to gain two electrons for a stable octet. Their common oxidation state, especially for oxygen and sulfur, is -2 in compounds. They also readily form covalent bonds by sharing electrons.

Metallic character increases down the group. Oxygen and sulfur are nonmetals, while selenium and tellurium are metalloids. Polonium and livermorium are metals. Many Chalcogens occur naturally as oxides, sulfides, or other compounds in the Earth’s crust.

Key Elements and Their Roles

Oxygen is the most abundant element in the Earth’s crust and atmosphere, central to biological and geological processes. It is essential for aerobic respiration in living organisms, acting as the final electron acceptor in energy generation. Oxygen also supports combustion, releasing heat and light, and is a fundamental component of water molecules, vital for life.

Sulfur is an abundant nonmetal found in nature, often in volcanic regions or minerals. It is used extensively in industrial applications, notably in sulfuric acid production, a widely used chemical. Sulfur is also employed in rubber vulcanization, improving its elasticity and strength. Biologically, sulfur is a component of several amino acids and vitamins, indispensable for living systems.

Selenium is a metalloid with unique electrical properties, valuable in electronics. It exhibits photoconductivity; its electrical conductivity increases with light exposure, used in photocells and solar cells. Its semiconductor properties also apply to rectifiers and photographic toners. In biological systems, selenium is a trace element, a cofactor for antioxidant enzymes, protecting cells from damage.

Tellurium is a rare metalloid primarily used in alloys to improve machinability and strength. It is added to copper and stainless steel to enhance their industrial properties. Tellurium compounds are also incorporated into cadmium telluride solar cells, efficiently converting sunlight into electricity. Its scarcity leads to higher cost and specialized applications.

Polonium is an extremely rare, highly radioactive metal, primarily an alpha-emitting isotope. It is found in trace amounts in uranium ores from the radioactive decay of natural elements. Due to its intense radioactivity, polonium has limited practical applications, mainly in antistatic brushes for removing dust from photographic film or delicate equipment. It has also been used as a lightweight heat source for thermoelectric power in space satellites.

Livermorium is a synthetic superheavy element, produced in laboratories through nuclear fusion reactions. It is extremely radioactive with an exceptionally short half-life, decaying almost instantly. Due to its instability and fleeting existence, livermorium has no practical uses outside of scientific research. Its study contributes to understanding the periodic table’s limits and superheavy element properties.